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Mechanistic insights into the impact of feed focus on product formation throughout acid-catalyzed conversion of glucose in ethanol


Catalytic upgrading of carbohydrates at concentrated feeds nicely conforms to the calls for for the economic deployment of bio-based fuels and chemical substances, however the majority of current explorations merely targeted on the utilization of dilute feedstock. On this contribution, the degradation habits of each dilute (20 g/L) and concentrated glucose (200 g/L) in ethanol medium was comparatively investigated by acid catalysis. The elevating of glucose focus from 20 to 200 g/L largely boosted the formation of water-soluble oligomers (WSO) as a substitute of stable humins (SHU). The activation power barrier for glucose-to-ethyl glucoside was elevated, whereas the barrier for ethyl glucoside-to-byproducts was decrease for concentrated glucose in comparison with dilute feed, thus downgrading the yield of ethyl levulinate (EL). The low solubility of glucose in ethanol favored the formation of glucose oligomers, and the excessive instantaneous focus of EL and 5-hydroxymethylfurfural (HMF) exacerbated the polymerization reactions with glucose, each of which is accountable to type extreme WSO at concentrated feed. Structural characterizations revealed that substituted furans, 2,5-dioxo-6-hydroxyhexanal (DHH) and its analogue are the principle fragments in WSO20, whereas WSO200 is essentially consisted of glucosyl models in addition to furanic and fragrant fragments linked with aliphatic models, resulting in the distinct construction of SHU from the 2 feed concentrations. This work renders insights into the impact of feed focus on product formation throughout acid-catalyzed ethanolysis of glucose, facilitating to plan optimum processes for valorizing concentrated sugars.

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